LIU Huanming The Steel Works No.2
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Benxi Iron and Steel Company
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Benxi
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ChinaYANG Zupan TIAN Yanwen Northeast University of Technology
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Shenyang
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China LIU Huanming
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Engineer
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The Laboratory of Steel Works No.2
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Benxi Iron and Steel Company
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Benxi
,
Liaoning
,
China
金属学报(英文版)
The interaction coefficients of Ca.Ti and Mg in the dilute Sn-based solution have been de- termined at 1500℃.Experimental measurements were taken by equilibrating the slag-alloy systems with metallic Sn as flux and graphite as reducing agent under Ar atmosphere mixed with different portion of CO.It was found that a considerable error may produce if the coefficients of ε_(Ca)~(Ca),ε_(Mg)~(Mg)and ε_(Ti)~(Ti)in the molten Sn were neglected when the activities of the components CaO,MgO and TiO_2 in the slags were estimated by this method.
关键词:
Sn
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null
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null
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null
Materials Chemistry and Physics
The corrosion behaviour of CortenA weathering steel has been investigated using a laboratory accelerated test that involved cyclic wet/dry conditions in Qinghai salt lake water diluted 30 times The characteristics of the rust layers on tested samples were observed by SEM and EPMA analyzed by IRS and XRD and studied by polarization and EIS measurements The weight loss was almost linear indicating that the rust layer had no retarding effect on the corrosion process The crystalline components of the rust layers consisted primarily of beta-FeOOH magnetite (Fe(3)O(4)) and gamma-FeOOH As the corrosion proceeded the amount of beta-FeOOH decreased while that of magnetite and gamma-FeOOH increased XRD EDAX and EPMA indicated that the complex corrosion products magnesioferrite (MgFe(2)O(4)) and iowaite (Mg(4)Fe(OH)(8)OCl 4H(2)O) probably existed in the rust layer in which case they will have had an important Influence on the protectiveness of the rust layer The results of electrochemical measurements showed that the rust layer exhibited high reduction reactivity which facilitated the corrosion of weathering steel in the wetting process The large rust capacitance and small rust resistance indicated that the rust layer had a loose and porous structure which provided poor protection (c) 2010 Elsevier B V All rights reserved
关键词:
Elements;Corrosion test;Electrochemical techniques;Electron probe;low-alloy steels;atmospheric corrosion;carbon-steel;electrochemical;impedance;room-temperature;rust layers;iron;mechanism;products;environment
WU Wei
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LIU Yue
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LIU Liu
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XUE Zhengliang
钢铁研究学报(英文版)
On the basis of the thermodynamic analysis and fundamental study in the laboratory, the equilibrium of the TiAlO system was investigated. The results showed that the equilibrium titanium content in the steel increased with the increase in the soluble aluminum content in the steel and the TiO2 content in the slag. Although the slag basicity decreased and Al2O3 content in the slag increased, the titanium content increased. Based on these results, the BOF smelting process of low titanium bearing steel was put forward.
关键词:
bearing steel;titanium content;experiment
LI Changsheng
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YANG Hua
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WANG Yanfang
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et al
钢铁研究学报(英文版)
Fe-3%Si steel strip was experimental produced by thin slab casting and rolling (TSCR) process in the laboratory. The microstructure and texture of hot rolled strip by different total reduction and rolling schedule was observed through EBSD technique and X-ray diffraction method. The changeable rule of texture density on the α、ε and γ, and fibers was analyzed. When the total reduction was increased from 82.9% to 97.1%，the gradient of microstructure and texture for A steel surface layer and center layer was found, {001}‹110› texture had higher intensity, and {001}‹110› texture was changed to{110}‹001›和{112}‹111›. The texture distribution with different reduction schedule for B steel was basically similar, but the Goss texture orientation density and volume fraction for B steel were higher, the hot rolling reduction schedule of C1 was effective to the formation of Goss texture. The research works were useful theoretical basis and reference data to develop electrical steel by thin slab continuous casting and direct rolling technology.
关键词:
Silicon steel;texture;hot rolling;thin Slab;Continuous casting and direct rolling
Y.Z. Lan
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S. Zhang
金属学报(英文版)
Steel slag is a byproduct produced in large amounts in the steel-making process. It is an important resource that can be effectively utilized. An experiment was described in which steel slag was tested as an adsorbent for the removal of phosphorus from waste water. Phosphorus removal depended on the amount of steel slag added, the pH value, the contact time, and the initial concentration. Under laboratory conditions when the added slag was 7.5g/L, the contact time 2h, and the pH value was equivalent to 6.5, over 99% of the phosphorus was removed; the experimental data on steel slag adsorption of phosphorus in the water fitted the Freundlich isotherm model. Steel slag was found to be very effective in adsorbing phosphorus.
关键词:
steel slag
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null
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null
Surface & Coatings Technology
Using a halide-activated pack-cementation method but at a temperature (600 degrees C) noticeably lower than normal, an eta-Fe(2)Al(5) coating and two delta-Ni(2)Al(3) coatings with and without dispersions of CeO(2) nanoparticles were developed respectively on a low-carbon steel and the steel pretreated with an electrodeposited film of Ni or Ni-CeO(2). The erosion-corrosion (E-C) performance of the three aluminide coatings during 100 h exposure at similar to 600 degrees C in a coal-firing laboratory-scale fluidized-bed combustor (FBC) was investigated, by mounting the aluminized samples onto a rig which maintained rotation for accelerating the relative impacting speed of flying solid particles (mainly SiO(2) bed materials). The eta-Fe(2)Al(5) and the CeO(2)-free delta-Ni(2)Al(3) coatings experienced an unacceptable recession rate. Compared to the two CeO(2)-free aluminide coatings, the CeO(2)-dispersed delta-Ni(2)Al(3) coating offered profoundly improved E-C resistance, because the latter coating was not only strengthened by the CeO(2) dispersion and grain refinement, it also could grow a more adherent alumina scale. (C) 2011 Elsevier B.V. All rights reserved.
关键词:
Erosion-corrosion;CeO(2)-dispersion-strengthening;Aluminizing coating;Grain refinement;Hardening;Reactive element effect;oxidation resistance;reactive elements;alloy-steels;water-vapor;power-plant;nickel;combustion;mechanisms;additions;behavior
LU Lu
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WANG Fu-zhong
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WANG Zhao-xu
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ZHU Guang-ya4
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ZHANG Xing-xiang5
钢铁研究学报(英文版)
Based on test data from the hot forge experiments on Gleeble 1500, a Kumar type constitutive equation for 33Mn2V steel is established. Applying this constitutive equation in commercial FEM software of MSC/SuperForm 2005, the piercing process of 33Mn2V steel in Mannesmann mill is then simulated. The modeling results visualized the dynamic evolution of equivalent stress, especially inside the workpiece. It is shown that the non-uniform distribution of stress on the internal and external surface of the workpiece is a distinct characteristic of processing tube piercing. The numerical model was verified by comparing the values of calculated force parameters of the piercing process with those measured in laboratory conditions. And it shows that the Kumar-type constitutive relationship meets the practical needs.
关键词:
33Mn2V
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constitutive equation
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tube piercing process
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thermo-mechanical coupling simulation
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FEM analysis
Corrosion Science
The early stages of the evolution of atmospheric corrosion of carbon steels exposed in both a laboratory simulated and a natural atmosphere environment in Shenyang have been observed by in situ scanning electron microscopy. In the case of laboratory cyclic wet-dry tests, even though the chloride content level is very low, filiform corrosion is initiated in the early stage. The filiform corrosion grows in random directions, forming a network of ridges. White nodules nucleate and grow on the ridges during continued corrosion and eventually connect with each other to form the initial corrosion scale. Pits were also found on the surface beneath corrosion products. In the case of a natural atmospheric environment, both filiform corrosion and other localized corrosion, such as pitting and inter-granular attack take place in the initial stage. It is obvious that there is variety of localized corrosion in the initial stage of atmospheric corrosion. (C) 2007 Elsevier Ltd. All rights reserved.
关键词:
steel;atmospheric corrosion;initial stage;localized corrosion;in-situ;iron;electrolyte;thickness
WEI Jihe Xi'an Institute of Metallurgy and Construction Engineering
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China.
材料科学技术（英）
The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied to the remelting of the high Cr steel 1Cr18Ni9(Ti).The laboratory data for the unsteady state A.C.ESR were analyzed and dealt with by the model.When the remelting process reached a steady state,an oxidant(Fe_2O_3 powder)or a deoxidant(Ca-Si powder or metallic Ca)was added to the slag bath.The results showed that this model is applicable to the remelting of stainless steel rather precisely, and it is expected that the model may offer a reliable basis for the control of composition during practical ESR of high alloy steel. Also,the oxidation of Cr in the steel must be noticed when its content is high;but it is entirely possible to adjust the Cr content of ingot within a considerable range,using a special technique by means of the slag-metal reactions during the remelting.
关键词:
ESR
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null
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null
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null
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null
